The plug is 50amps; fine. But what about the wire leading to the plug from the engine compartment? In fact if memory serves when I last checked on my Ford the fuse and/or relay was only 30A, and I'm not sure if that was just for like trailer brakes. So you'd be running the risk of overwhelming the wiring, and certainly blowing the fuse, with many compressors. Not to mention the voltage drop. Might be worth it to run another heavier gauge wire back there, with appropriate circuit protection, if you're gonna go to the trouble of using that socket. I ran welding wire back to run a small winch off an anderson plug; worked great. Sometimes you can find an easy route for the wire.
Or just use your jumper cables to extend the clamps from the battery to the air compressor. We do that all the time, and you may be carrying them already. Even used a heavy duty extension cord that we hacked for solar panel use. You could make it all cool by installing power poles on both ends.
I ran 6awg marine grade wire. I checked the charts, with the distance run, and planning for 40 amp, no issues should be had. You bring up a good point, "do you homework and don't take shortcuts." You would hate your rig catching on fire.