A couple of things for your to consider -
As
@DiploStrat already mentioned, MOST quality LiPo batteries have an internal BMS that will protecting them from charging when below their “safe” temperature (around or a little above freezing) but will still allow you to discharge, to allow for continued use but could also power a very small heating pad to help maintain the battery above the required temperature.
A battery is a really large, dense mass so if its well above the “safe” temp, it will usually stay above that temperature for some time, especially if you are continuing charging and discharging the battery. Simply running current in or out of the battery will raise it’s internal temp.
In my experience, the biggest issue is that in cold temperatures, if I continue using the batteries even if I’m not in the truck and heating the space (think fridge, lighting, etc.) and therefore discharging the batteries, but unable to charge because I may have gone below the “safe” temp.
I’ve only gotten myself in “trouble” when I was away for a couple of nights and the battery weren’t being charged at all either because I didn’t have DC-to-DC going or solar charge, while the habitat temperature kept dropping.
The worst that ended up happening was that the battery stopped charging because of the temperature and fully discharged (well, until the BMS shut it down).
Little or no harm, except that it was a pain to get the battery back above the “safe” temp and charging, since now my whole system had disabled charging. After it happened a second time, I’ve been EXTRA careful and carry a Noco Genius charger that allows me to partially charge the battery before connecting it back to the truck’s system.
Hope this helps.
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