Excuse my ignorance but can I monitor both solar charging and the charge from the starting battery/alternator from one smart shunt?
Depends on the device, guessing, probably, if not you could switch the circuit so that each can or could be observed. A "shunt" simply impedes or diverts part of the current, generally for another circuit. It being "smart" may just automatically adjust the level of current under certain conditions, that might include a meter to observe voltage/amps/watts. Read the specs on the device.
You asked above about panel sizes, go with the highest watt size at a usable physical size. 100 watt will likely be smaller in area than 2- 50 watt panels due to the physical sizes of panel dead space, frames and mounting hardware needed.
1-100 watt panel isn't much for a week outback. Depends what you use it for and how often, but your starter battery shouldn't go dead just sitting hooked up to 100 watts.
Have you computed the watts needed for your intended and expected use? That's where you need to begin. What do you need to operate and for how long?
That tells you the size of the battery bank and panels required, which then leads you to the design and gizmos required for operation.
BTW, IMO, going the solar generator route, Bluetti, Jackery, etc. with panels is the least expensive/easiest way to go. Having an extra battery is also a good idea. (The cheapest, but more difficult way is to build your own batteries). Example, A Bluetti EB2A is 200 Ahr and probably is much more expensive than the battery you ordered, no switches, meters, shunts, gizmos needed and about the same size as the battery.
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