For LFP longevity you don't want a charge rate higher than .5C anyway.
That means recharging in under 2 hours.
If your super fancy heat-managing alternator setup (you do have that right? I think not)
**really can** output 200A continuously
(I think not)
(is your top priority to capture all that energy? why?)
Then install a bank over 400Ah in size, not piddly drop-in junk but a proper prismatic bank.
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With regard to voltage, for longevity
normal daily cycling should just stop at 3.45Vpc, or 13.8V for 4S. Maybe 14V would be OK at such high current rates, long as you do "just stop", no CV Absorption time.
The Sterling BB series is what is needed here, **not** any product that someone stuck a "Lithium" label on and gives you zero adjustability.
To handle 200+ actual charging amps (really?) then you need to stack four of them, since Charles has not yet released the higher-than-60A models.
That is the only practical safe and reliable way to give the bank what it needs to last a long time, **and** to protect the alt setup from LFP's rapaciously large CAR / current demand.
Which yes is maintained very high up the SoC curve, the whole reason it is brilliant compared to lead, which requires 5-7 hours to get back to 100% Full.