May not be worth the effort
What kind of vehicle are we talking about and how big a battery bank?
Adding a second alternator could be a lot of work especially as you would also need to set up some form of regulator. If you choose to go this way, check with local shops that cater to the head busting car stereo crowd as they do a lot of multiple alternator installs.
It might be much easier to simply replace your current alternator with a high output model. A quick search of the 'net will turn up any number of these which are simply plug and play. (And do replace the drive belt.)
An alternator in the 150-200A range, coupled with an intelligent relay and properly sized wiring is probably all you need, especially if you have a modern vehicle whose electrical system runs in the 14-15v range. And you can determine that with a voltmeter.
For any battery bank of under 200Ah or so, you will be hard pressed to sustain a charge rate of over 100A for very long.
Don't make this harder than it has to be.