It looks clean from the under the hood shot. I would just go over it closely, change all the fluids and etc unless they can prove they've been done recently.
I think you could daily drive it as long as your commute is pretty short. I love driving mine. I would daily drive it but due to the nature of my work I have to make regular trips from SA to Austin, Houston, College Station and etc.
If that particular one doesn't work out, I know someone in New Braunfels with a clean 95' LWB for sale.