Love the spec you've laid out, & the build is looking great so far!
To a certain extent your corner selection would be guided by the panels you are putting together. As you mentioned, a habitat assembled with structural composite panels wouldn't necessarily need a frame at all. At that point the determining factor for the corners is what sort of "trouble" you're planning to get into relative to the amount of corner protection you feel you need. If weight is a primary consideration, then the slight loss of protection in going with .100 vs. the 1/8" isn't really that significant, & the pieces will be marginally easier to form. Some good discussion on edge protection here:
https://forum.expeditionportal.com/threads/custom-extrusions-for-frp-panels.229840/#post-2985692
Keep in mind also the attachment method you are planning, in case a corner is damaged to the point that you want to replace it. There's also the issue of differential expansion, which can usually be accommodated by the thickness of your adhesive.
So, what manner of panel are you planning to put together (or did I miss that somewhere?).