I have 8 3.2 v 100ah cells.
This raises an interesting issue that is not widely discussed, that being the resting voltage of LiFePO4 cells.
There are numerous companies out there that offer charging solutions for LiFePO4 batteries. Their sales pitch is normally that their product includes a "lithium charge profile", so it must be appropriate, right?
The resting voltage for my Winston cells is 3.6v, so can I use the same charging device as someone that has LiFePO4 cells with a resting voltage of 3.2v? I would argue that you cannot.
Basically... not all lithium batteries are created equal, so a "one size fits all" solution is a bit of a pipe dream.
Without hijacking this thread and making it all about LiFePO4 batteries, unless you intend on buying a complete "lithium system", of which there are some very nice, but expensive ones available, my recommendation (for what it's worth) would be to buy charging products that are user programmable. That way you can set the charging rate to something that is appropriate to the specific LiFePO4 cells you have.
Still researching best setup.
Having all of the cells in series is the simplest for monitoring the individual cells, which you need to do (via a BMS), but this setup may not be practical. Electric vehicles run numerous banks of batteries in a series/parallel setup, which is an accepted thing to do. You just have to decide on what output voltage suits your needs best, then wire the cells together accordingly.