Thanks Owen, I've done a bit of research and it appears possible with some of the modern primers and good surface prep, I have some offcuts so can do a test and see.
The PE is easily damaged so need to protect it from flying stones, not worried about hitting boulders as much.
Also thanks Julian. The ones between the rails might be ok but I have some right behind the LH front wheel as well, hadn't thought of ply, cheap and easy to work with.
Cheers Steve