Aluminum would not need anodized, assuming you don't use some corrosion prone alloy. Plenty of factory cast aluminum intakes and heads without anodizing. AL forms a protective Aluminum oxide layer within seconds of exposure to air.
PVC (unless its glass reinforced) would be fairly brittle. It welds quite well though. I see no reason it couldn't be used, as long as the operator understands it will crack if you bash it. Obviously it needs to be painted unless its been UV stabilized. Thick walled (SCH80) pipe is pretty tough. It would make for a fairly large OD though.
Wound fiberglass pipe is also a good option. Not sure if its available in the right size. Joints would be pretty simple using glass and resin to build them up. May not be the prettiest depending on surface finish. Paint would be required unless a UV resistant resin is used.
Any good exhaust shop with the right equipment can bend thin wall tubing to your needs. The aluminized exhaust tubing is quite durable. Paint as desired. The finish product could also be plated with stainless if desired. Surface finish would need to be very smooth. Consult with your plating shop before doing the work, as they will have input on material types and acceptable under coatings.