Well, the only other thing is brake fluid. Properly bled the system I assume?
Brake fluid absorbs water from condensation inside the system and that lowers the boiling point of the fluid. So it has to be completely flushed out and replaced every so often.
More than once I've had a "brake job" done at a shop and they didn't bleed the brakes and when I mentioned it they said there's no need to bleed if they didn't open the system and let air in.
Made we want to slap them upside their idiot heads.
You using DOT 3 or DOT 4?
I can maybe see the fluid getting hot and expanding if it has some water in it, but I can't see it being caused by the hydraulic power booster. Maybe a brake line too close to the exhaust or some such thing.
Um...I just remembered an incident from a long time back that probably has nothing to do with anything...
Down in Baja, a guy in our group got a brake line nicked from a rock and lost all his fluid. Pinched off the line so he could keep going, but turned out he didn't have any brake fluid. We all checked our trucks and none of us had any either. D'oh.
Someone says, "I got power steering fluid. Think that will work?" We all look at each other and shrug. "Dunno."
So the guy says screw it and puts the power steering fluid in his brake system.
He could drive for like 20 minutes with the brakes getting tighter and the truck getting slower, then he'd have to park and let it cool off for an hour and then do it again.