Having re read this and studied the pictures, if that silver pipe is indeed going back to the radiator, then the cap (with the chain on it) should I think just be a flat cap with seal, and not a relief cap, as the silver pipe is the bleed return pipe (which has to return to just above the water line in the header tank unrestricted).. You can use this cap to fill, and fill to the lower edge of this cap. This then means that the higher cap to the right of the pic would be the pressure relief cap. This cap should have a spring in the center and be able to release pressure if it needs to, which in turn gives plenty of expansion room above the water level.... Is there a small outlet pipe anywhere on the filler neck of the higher cap that we can't see in the pic? If so, this needs a short length of hose on it that should/could lead into an expansion bottle (old coke bottle will do). The small hose should go to the bottom of the 'expansion' coke bottle, which allows excess coolant to escape if needed, but then allows it to be siphoned back in as the system cools again... That's how I see it working.... Mine has 2 caps... The lower one is never opened, and the higher one is the pressure release cap and doubles as the fill cap... Its usually high enough that the water level never gets to it when expanding. Hope this makes sense and good luck on your water loss quest.