For comparison, I have a National Luna DC Powerpack with a 100ah Battleborn. The DCDC charger is rated at 25 amps. NL provides a 20 foot 6mm (between 5 and 6 awg) cable to run from the starter battery into the box where the DCDC lives. To which I added another 6 feet of 6awg due to my run distance. I have a Victron smart shunt on the battery and can see that it does get the full 25 amps. No heating of the cable. 4 awg would certainly be great, though heavier and more expensive. 6 awg would likely be just fine and easier to work with. Of course, depends on your setup and the distances. YMMV!