First of all, welcome to the forum
Sylvanus41, and to the world of private ambulance owners!
I'll try to answer your questions to some extent.
1. Windows - Most of the wiring comes into the module from underneath behind the driver's seat and up to the electrical panels. After it leaves the electrical panels, it travels to the various devices to the rear and sides above the ceiling. Generally, there is a wiring chase on the driver's side in the ceiling that runs from front to back with wiring branching out from it, similar to nerves coming out of your backbone. There will be some wires in the wall, but normally only if there is a device needing power in that space, either inside or outside.
The walls are constructed out of 2"x2" extruded aluminum square tubing, covered by 1/8" aluminum sheeting on the outside, and since your's is a 1996 model, probably 3/16" or 1/4" paneling on the inside. The tubing is arranged in a grid pattern on 14" or 16" centers. It is designed this way because this frame also functions as a roll cage in case the unit flips over in an accident. According to the government regulations, that frame is supposed to be able to support the entire weight of the ambulance with it sitting on it's top. As far as removing any of the frame to mount windows, I would make my cuts and try to add and/or reposition the frame members to form a box around the window, which most of them will require anyway. Then add vertical pieces to maintain the structural integrity.
Here are a few pictures of another brand in the construction phase to help you understand. Note the grommets in the tubing anywhere wires must pass through. These are often sealed with silicone also, which makes moving or pulling additional wires almost impossible unless you have the walls open.
2. Electrical System - This one is not so easy. This topic has been discussed many times on this forum by ambulance owners, to one extent or another. To my knowledge, this information is not in any one place either. All wiring is done to meet specific codes, regulations, and requirements, but each manufacturer is slightly different. Your best bet is to contact the manufacturer and see if they can provide you with a wiring diagram of some sort. Being it's a 1996 model, that may be difficult since their records may not have been computerized yet. Your second best bet is to look in the
Other Custom Expedition Camper section, where all of the ambulance builds are, and find one with a unit similar to yours. You may find answers in their build thread or you can ask them for help.
There are a lot of us on here that are fairly knowledgeable about the electrical systems on ambulances, but to write a complete step by step manual on how they are wired is impossible. That's what electrical engineers are for.
I'll see what I can find and get back to you in a few days.
After I first started building mine, one of the things I found that helps, is to take good quality pictures of everything both inside and out, and include detailed pictures also. Not only does this help you reassemble something after you take it apart, it gives you ready access to pictures to include in a post when you're asking a question about something at 11:00 pm. and it's raining outside.
Looking forward to seeing some pictures of your rig after you get your build thread started!
~Pat