DWH is correct. By adding the calorifier in the loop, it acts as a energy (thermal) storage device that can absorb and store the heat produced by the hydronic heater. A side effect is prolonged run times which prevents the hydronic heater from starting up and only running for a very short period before shutting down. The same thing will happen in an improperly bled system when the circulation pump catches a pocket of air and the flow of coolant is interrupted.
Here is a simple example of a single series circuit that might work. By using the calorifier with the addition of a circulation pump connected to a thermostat, it can allow you to slowly take energy (thermal) from the calorifier and dissipate it by way of the active or passive radiator(s) in your system. When turned on, the hydronic heater is constantly checking to make sure the coolant is maintained above the set point (~85 degrees C) and restarts the combustion chanber when needed - dumping additional energy into both the calorifier and the radiator(s). Some hydronic heaters might be able to be programmed to run the on board circulation pump (if so equipped) to do the above (YMMV).
A more complex series/parallel or parallel circuit could add more user control to the system if desired.