Look back in this thread and there are some hard numbers about heat and melting sync line. It just CAN'T happen with this type of soft shackle and aluminum block. To damage synthetic line it needs to be too hot to touch.
True, you aren't going to melt it and it's unlikely that you'll get it warm enough to reach critical temperature (Dyneema has to be kept below 150°F to avoid damage).
But
can't is a strong word since there's obviously some non-zero amount of friction involve. The rule of thumb threshold to sustain a burn is 70°C (~158°F) and indefinite heat tolerance is 45°C (~110°F). So we're sitting right in the region between comfortable and too hot to handle (being immediate pain) for most people.
Do you know for a fact that in use these temperatures are valid? You can't hold your hand on a spinning ring. Has Sampson a technical paper on using low friction thimble rings in this way and whether perhaps sustained lower temperatures are acceptable? I don't remember if anyone's done temperature experiments to know, particularly in the fixed shackle (that's the one that seems vulnerable) and whether the temperatures are uniform through the whole cross section. The skin of the rope might not be the same as the core. If they have and we can say with reasonable certainty then it's a moot point.
Ultimately, the great thing is you're allowed to have your opinion and I mine to what trade-offs and risks we're each willing to accept. If you feel comfortable with rigging this way that's fine. I've never argued it wasn't strictly safe (and if so that was an incorrect assessment, it seems basically safe). I just don't view mass as an absolute penalty when it can be trusted and when its wear and service life is considered.