A vehicle you might want to look at just from a data-collection standpoint is the Astro/Safari van.
Depending on the year of manufacture, the AWD models were equipped with either a viscous-coupled (mechanical) center diff (early vans), or an electronic actuated center diff (later vans) that used a shift motor to basically lock and unlock the diff in response to inputs from the ABS sensors, etc. Additionally, there is a statistically-significant population of Astro/Safaris running around with true locked transfer cases (most of us having done so for the purposes of gaining low-range, etc.)
Generally, the consensus amongst the community is this:
The viscous-coupled transfer case offers the best performance on snow/ice and other low-friction surfaces. The supposition is that because the VC is biasing the center diff along a continuum of torque, there's generally a smoother engagement and smoother behavior which translates to better road manners. Anyone with a Subaru can attest to this behavior because generally Subaru achieves the same effect (although through a variety of methods - either a viscous coupler or an electronically-controlled clutch pack that pulses with high frequency) of biasing the torque front to back along a continuum.
The GM electronic transfer cases do not contain a clutch mechanism, rather they simply engage to 100% locked (50%/50% torque distribution) and back to unlocked (100% rear torque) on and off. This happens very quickly, but does not happen as fast as Subaru's clutch pack, so you don't get as smooth an engagement. That said, this system is still quite manageable in slippery conditions. However, owners who've had both in the right conditions do indicate the viscous behavior is better.
Finally, there's those of us who've modified to a fully locked TC, and that seems to be a mixed bag. On the one hand, it's always engaged (within the span of a few seconds or minutes, at least) so there's no "change" in behavior mid-corner. On the other, this setup seems to be somewhat more susceptible to other influences, like the behavior of the rear differential. Those running a locked 4wd TC, along with an "automatic" locking rear diff, like a Detroit Locker, etc., report borderline scary behavior whereby the van will "push" mid-corner if power is not applied smoothly by the driver. This is a more common scenario than I'd like, since there's no selectable locker available for the Astro/Safari's 7.625" rear. Those with limited-slip (Eaton clutch or G80/Gov-Lock types) report more "tame" behavior under the same conditions.
In Summary: AWD and full-time center diffs DO seem to have a behavior advantage on the slippery stuff. Behavior of a fully-locked part-time transfer case may be tolerable, or scary, depending on a variety of other factors.