Less leverage=more pressure required to make same stop-therefore more vacuum?
By putting in a larger vacuum tank you will get a greater vacuum reserve, but it will not give you a deeper vacuum, hence, this will not actually improve the braking effort.
It was mentioned previously... if you want "better braking", a bigger vacuum booster will help.
A brake vacuum booster works by using vacuum over a diaphragm, which in turn increases the pressure applied to brake fluid in the master cylinder when the brake pedal is depressed. If you increase the size of the diaphragm then you increase the pressure effect it has.
However... like with increasing horsepower in an engine, using a larger vacuum booster will add additional stresses which can lead to a reduced lifespan, or at worst, a component failure.
If you were to increase the vacuum booster size you should also ensure that all of the other components in the braking system, like the seals and brake lines, are in very good condition, as these will be under more stress if the pressure in the brake lines is increased.
I have heard that some brake shoes work better than others, which is another option for improving braking efficiency.
At the end of the day, I agree with Julian... drum brakes suck!