On insulation: Spray in foam is one way to go. I have no clue what is available down under, but I can get R-7.4 easily here in the states in a 2 part canister pair.
Another thing to think of is radiant heat gain. Sol can be brutal. If you have a reflective foil layer just under your outside skin it will do wonders for keeping the worst of the heat gain at bay. Remember that heat will radiate up from the ground too, not just Sol in the sky. The trick is it needs to be separated from the outside skin by an air gap. That gap can be maintained by a netting sandwiched in between. I haven't done this and haven't heard of it being done yet: I was thinking of using a high temperature adhesive to glue the netting to the inside of the outside skin. Then I'd glue the foil on to the netting. Actually if you soak the netting in adhesive it will glue to the skin and then the foil can be applied to the inside. Finally I'd spray the foam in after the adhesive has setup. The idea needs some testing to see if it will hold up to abuse and to see if the foil gets pressed against the outside skin by the foam. The adhesive needs to handle 250F without loss of strength. Tough to find.
Second Skin Audio seams to have found it for applying their sound deadening mats. I just haven't been able to get thier site to load tonight.
More on reflective layers:
TekFoil is a bubble wrap like insulation product. It basically is a layer or two of bubble wrap with reflective foil faces. Bubble wrap insulation it's self isn't all that good at night, but it is better than nothing and it is very light. I would look at the foil/bubble/poly versions for use in AU. The poly face when put to the inside won't reflect interior heat back in. The Handi-Foam spray in foam this place also handles is only R-4 per inch. There is much better out there.
For the ultimate in reflective use gold foil. Gold is the best at reflecting IR radiation. The kicker is now your rig looks like a million bucks...
On cooling... In the past few years a good number of 12VDC and 24VDC powered air conditioners have hit the market. They are being mainly sold to the trucking industry as they are more efficient than engine driven ones and with a big battery bank you can run them overnight without running the engine. That means big diesel savings when truckers are sleeping in the cab. One company was saying it only took a 24VDC 220AH battery bank for 50% duty cycle for 8 hours. To a trucker that is 2 8D batteries which is a common truck battery size. Recharge is done while the truck is driving during the day.
Autoclima seams to sell generic units to cool buses, RVs, etc. They are Italian. There are other manufacturers out there. Oh, the other reason they are being put into trucks. Efficiency. An engine driven compressor wastes allot of energy. The DC powered ones only run when they are needed and thus can save as much as 5% on fuel use on top of the over night fuel savings. Fleet managers eyes light up when they see savings numbers like that. I've thought of ripping out the engine driven compressor and replacing it with a 24VDC alternator. It would charge a 24VDC battery bank and supply power for a 24VDC air conditioning unit as well as other electrical loads. If done with the same voltage as the primary alternator it provides redundancy for the alternator. If the battery bank is made of 3 or more batteries it can be pulled out and reconfigured in series for emergency welding. Even if you don't have enough battery capacity for running A/C over night consider having three or more batteries so you can do welding. Consider using 3 35AH batteries in parallel instead of one 100AH battery.