I intended to not take this any further, but I can see that I need to elaborate at least a little.
The way I see it, air tanks are round with rounded ends for very good reasons. When compressed anything became possible people learned a lot about why tanks failed. Usually from disastrous and occasionally from deadly events.
At 125 psi you're *just* at the pressure where the various compressed gas regulations, stds, & codes (DOT, ASME, SAE, etc.) take effect. To my knowledge none of those bless a flat sided/ended tank.
A balloon doesn't take on the shape it does by chance. Pump up a flat capped square or rectangular steel tube and it too will want to take on the balloon shape. Even if the pressure isn't high enough for it to actually take that shape, it's still trying to do so. That puts a lot of stress in the tube corners and in the cap welds.
To me the convenience just isn't worth the potential catastrophe.
With that, I'll let it go.